Separation of Americium from Plutonium-Solvent Extraction Raffinate and Conversion to Americium Oxide

Electrochemical Separation of Curium and Americium

The objective of this project is to develop a method for the separation of Am from Cm based on electrochemical techniques. Electrochemical systems that allow the thermodynamics of actinide and lanthanide complexes to be systematically evaluated and tuned will be examined. The influence of complex formation on the ability to selectively isolate a given species electrochemically will be evaluated...

Plutonium and Americium in the Cephalopod Octopus vulgaris

Radiotracer experiments using the photon-emitters 2 3 7 ~ and 2 4 1 ~ m were performed to examine uptake, tissue distribution and retention of plutonium and americium in the cephalopod Octopus vulgaris Cuvier. A 2 wk exposure in contaminated sea water resulted in twice as much 2 3 7 P ~ being taken up by whole octopus as 2 4 1 ~ m . Immediately following uptake approximately 41 % and 73 % of th...

Relativistic density functional theory modeling of plutonium and americium higher oxide molecules.

The results of electronic structure modeling of plutonium and americium higher oxide molecules (actinide oxidation states VI through VIII) by two-component relativistic density functional theory are presented. Ground-state equilibrium molecular structures, main features of charge distributions, and energetics of AnO3, AnO4, An2On (An=Pu, Am), and PuAmOn, n = 6-8, are determined. In all cases, m...

Transfer of plutonium, americium and curium from fallout into reindeer after the Chernobyl accident

Several reindeer tissue samples were analysed for transuranium elements following the Chernobyl accident in 1986. Pu, Am and Cm were separated using coprecipitation and anion exchange steps, and measured with alpha spectrometry. The activity concentrations of Pu in reindeer liver found in this study (0.0094–0.062 Bq kg d.w. [= dry weight]) are low compared to the concentrations found in the 196...

The unveiled states of americium.